物理化学实验指导

第一部分 绪论(Part One Introduction)

一、物理化学实验的目的和要求

二、物理化学实验的安全知识

三、物理化学实验的设计思想

四、误差理论和有效数字

五、实验数据的表示法和处理

1．Objective and requirement

2．Physical chemistry laboratory safety

3．Rules for designing of the physical chemistry experiment

4．Error theory and significant figures

5．Data reporting

第二部分 实验(Part Two Experjments)

实验一 燃烧热的测定

Experiment 1 Heats Of Combustion

实验二 溶解热的测定

Expenment 2 Heats of Solution

实验三 凝固点降低法测定摩尔质量和渗透压

Experiment 3 Molar Mass and Osmotic：Pressure by Freezing Point Depression

实验四 液体饱和蒸气压的测定

Expenment 4 Saturated Vapor Pressure of Pure LJquids

实验五 反应平衡常数及分配系数的测定

Expenment 5 Equilibrium Constant 0f Reaction and PaItitiml Coefficient

实验六 完全互溶双液系平衡相图的绘制

Expenment 6 Phase Diagram of a Miscible Binary Liquid Svstem

实验七 双组分简单低共熔体系相图的绘制

Expenment 7 Solid-liquid Binary Phase Diagram

实验八 三组分液-液系统相图的绘制

Experiment 8 A Ternary Phase Diagram for a System of Three Liquids

实验九 电解质水溶液电导的测定及应用

Experiment 9 Measurement and Application of Electrolyte Solution

Conductance

实验十 电动势法测溶液pH和反应热力学函数

Experiment 10 Determinations of pH of Solution and Thermodynamic Functions

by Electromotive Force Measurements

实验十一 一级反应速率常数的测定

Experiment 11 Rate Constant for First Order Reaction

实验十二 碘化钾与过氧化氢反应的速率常数及活化能的测定

Experiment 12 Kinetics of Reaction between Potassium Iodide and Hydrogen

Peroxide

实验十三 丙酮溴化反应速率常数的测定

Experiment 13 Rate Constant and Activation Energy of the Bromination of

Acetone

实验十四 乙酸乙酯皂化反应速率常数及活化能的测定

Experiment 14 Rate Constant for the Saponification of Ethyl Acetate by

Conductometric Method

实验十五 最大泡压法测定溶液的表面张力

Experiment 15 Surface Tension of Solutions by Bubble Pressure Method

实验十六 固体在溶液中的吸附

Experiment 16 Adsorption of Solids in Solution

实验十七 乳状液的制备和性质

Experiment 17 Preparation and Properties of Emulsion

实验十八 溶胶的制备及性质

Experiment 18 Preparation and Properties of Sols

实验十九 黏度法测定大分子的平均相对分子质量

Experiment 19 Average Relative Molar Mass of the Macromolecule by

Viscosity Method

实验二十 纳米材料的合成与表征(综合设计性试验)

Experiment 20 Preparation and Characterization of Nanomaterials

(Multi—designing Experiment)

实验二十一 药物稳定性及有效期测定(设计性实验)

Experiment 21 Determination of Drug Stability and Shelf Life

(Designing Experiment)

实验二十二 固体药物常规理化常数的测定(综合设计性实验)

Experiment 22 Physical and Chemical Constants of Drugs

(Multi—designing Experiment)

附录(Appendices)

常用物理化学数据表(Reference Data of Experimental Physical Chemistry)

参考文献(References)