复合材料的表征

Preface to the Reissue of the Materials Characterization Series x

Preface to Series xi

Preface to the Reissue of Characterization of Composite Materials xii

Preface xiii

Acronyms xiv

Contributors xv

X—RAY PHOTOELECTRON SPECTROSCOPY （XPS） AND

ELECTRON SPECTROSCOPY FOR CHEMICAL ANALYSIS （ESCA）

1.1 Introduction 1

1.2 Fundamental Principles： XPS and ESCA 2

1.3 Applications of XPSIESCA to Composites 9

Fibers 10， Polymer Matrix Materials 13， Composites 14，

Failure Modes 19

1.4 Summary 23

RAMAN SPECTROSCOPY

2.1 Introduction 26

2.2 Normal Raman Scattering 27

2.3 Surface—Enhanced Raman Scattering 28

2.4 Polymer—Metal Composites 29

Adsorption of Polymer to Metal 29， Adhesive—Adherent Interactions 33

2.5 Polymer—Polymer Composites 38

Polymer—Polymer Interdiffusion 38， Surface Segregation in Polymer Blends 39

2.6 Fiber—Polymer Composites 39

Stress Transfer at Interfaces 39， Surface Structure of Carbon Materials 41

2.7 Summary 41

NMR IMAGING OF COMPOSITES

3.1 Introduction 44

Basis of NMR Imaging 45， Relaxation Parameters in NMR Imaging 46， Pulse Sequences for Generating Contrast in Imaging 47， Resolution in NMR Imaging 48， Utility of NMRI 49， Image Processing 49

3.2 Advanced Imaging Techniques 50

Chemical Shift Imaging 50

3.3 NMRI of Solids 52

Design Limitations of High Performance Fiber—Reinforced

Composites 52， Interracial Bond Quality and Defect Characteristics

of Composites 53， NMR Imaging as a Composite Inspection

Technique： Detection of Internal Voids 54， Detection of Nonuniform

Dispersion of Filler 55， Aging of Composites 56， MRI as an

Environmental Monitoring Technique 58， Adsorption of Liquids in

Polymers 58， 1H ImagingofSolids 58， 13C ImagingofSolids 60

3.4 Conclusions 61

NMR STUDIES OF ISOTOPE—ENRICHED SPECIES AT INTERFACES

INVERSE GAS CHROMATOGRAPHY

DIELECTRIC SPECTROSCOPY

IMAGING AND CHARACTERIZATION OF MATERIALS BY THE

NEW SCANNING PROBE TECHNIQUES （STM/AFM）

ELASTIC AND VISCOELASTIC BEHAVIOR OF COMPOSITES

INFRARED SPECTROSCOPY FOR COMPOSITES

《复合材料的表征/材料表征原版系列丛书》涵盖了专门应用于复合材料的先进表面分析技术，围绕复合物及聚合物基复合物的光谱表征，这本书包括对复合材料研究非常有用的技术，以及一些有前景的新技术如STM/AFM、特殊拉曼光谱。每章会介绍一门特定的技术，提供基本的背景信息、技术理论、应用实例，包括未来最先进的应用。