聚合物多层次结构中稀土络合物的光谱性质

Chapter1Synthesisandcharacterizationofrareearthcomplexdopedpolymers

1.1Synthesisofrareearthcomplexdopedpolymer

1.2Uniformityandthermalstabilityofrareearthcomplexdopedpolymer

1.2.1X-raydiffractionofrareearthcomplexdoped

1.2.2Near-fieldscanninganalysisofrareearthcomplexdoped

1.2.3ThermalpropertiesofrareearthcomplexdopedPMMA

Chapter2SpectroscopicpropertiesofrareearthcomplexdopedPMMAandtheirJudd-Ofelttreatment

2.1Thetheoryofspectroscopicanalysis

2.1.1Energylevelanalysisandnephelauxeticeffectofrareearthcomplexes

2.1.2Judd-OfeltTheory

2.2SpectroscopicanalysisofNd（DBM）3PhenandNd（DBM）3（TPPO）2inPMMA

2.2.1EnergylevelanalysisandnephelauxeticeffectofNd（DBM）3PhenandNd（DBM）3（TPPO）2inMMAand

2.2.2RadiativepropertiesofNd（DBM）3PhenandNd（DBM）3（TPPO）2dopedPMMA

2.3SpectroscopicanalysisofEucomplexesinPMMA

2.3.1FluorescenceofEucomplexesinPMMA

2.3.2RadiativepropertiesofEucomplexesinPMMA

2.4SpectroscopicanalysisofErcomplexesinPMMA

2.4.1FluorescenceofErcomplexesinPMMA

2.4.2EnergylevelanalysisandnephelauxeticeffectofEr（DBM）3（TPPO）2inPMMA

2.4.3RadiativepropertiesofEr（DBM）3（TPPO）2dopedPMMA

2.5SpectroscopicanalysisofPrcomplexesinPMMA

2.5.1FluorescenceofPrcomplexesinPMMA

2.5:2EnergylevelanalysisandNephelauxeticeffectof

Pr（DBM）3PhenandPr（DBM）3（TPPO）2inPMMA

2.5.3RadiativepropertiesofPr（DBM）3（TPPO）2dopedPMMA

2.6SpectroscopicanalysisofSmcomplexesinPMMA

2.6.1FluorescentanalysisofSmcomplexesinMMA

2.6.2EnergylevelanalysisandnephelauxeticeffectofSm（TTA）a（TPPO）2inMMAandPMMA

2.6.3RadiativepropertiesofSm（DBM）a（TPPO）2inMMAandPMMA

Chapter3RectificationofexcitationwithbathochromicshiftduringemissionmeasurementofEucomplexes

3.1Bathochromicshiftduringfluorescencemeasurement

3.2TheoreticalmodelfortreatmentofBathochromicshift

3.3Predictionofbestexcitingwavelengthforfluorescencemeasurement

Chapter4FluorescenceenhancingofrareearthcomplexesinPMMA

4.1FluorescenceenhancementofEu（DBM）3PhencodopedwiththeotherrareearthcomplexesinPMMA

4.2FluorescenceenhancementofSm（DBM）3PhencodopedwithotherrareearthcomplexesinPMMA

4.3ModelforluminescenceenhancementinPMMAcodopedwithtwokindsofrareearthcomplexes

4.3.1Intra-molecularenergytransferwithineachcomplex

4.3.2Inter-molecularenergytransferbetweencomplexes

4.3.3QuantitativemodelforluminescenceenhancementofEuxTby-PMMA

Chapter5EffectsofsynergeticligandsonradiativepropertiesofEu（TTA）3nLdopedPMMAandLBfilms

5.1TheradiativepropertiesofEu（TTA）3nLdopedPMMA

5.2TheradiativepropertiesofEu（TTA）3nLdopedLBfilms

5.2.1FluorescencepropertiesofEu（TTA）3nLdopedLBfilms

5.2.2ModelforsupermolecularstructureofLBfilmscontainingrareearthcomplexes

5.2.3FluorescenceofAA/Eu（TTA）3（TPPO）2LBfilm

Chapter6ThreedimensionalmemorythroughsubmicrometervoidsformedwithinSm（DBM）3PhendopedPMMA

6.1Materialandequipmentformultiphotonrecordingbyfemtosecondlaser

6.2Recordingandreadingofthree-dimentionalopticalstorageinSm（DBM）3PhendopedPMMA

Chapter7Nanocompositescomposedofrareearthcomplexesandsilvernanoparticles

7.1J-aggregatesofrareearthcomplexesformedonthesurfaceofsilvernanoparticles

7.2EffectsofAgcolloidalnanoparticlesonluminescentpropertiesofEu（l]I）-diketone

7.3NanocompositecomposedofEu（TTA）3Bipy/Tb（TTA）3Bipy/SilverNanoparticles

Chapter8Modulationinluminescenceofrareearthcomplexesdopedinphoto-responsivepolymer

8.1Photo-inducedopticalanisotropyandpolarizedemissionofeuropiumcomplexdopedazobenzenepolymerfilm

8.2Reversiblemodulationinfluorescenceintensityofasinglevesiclecomposedofdiblockazo-copolymerandEu（DBM）3Phen

Chapter9Polymeropticalfibersdopedwithrareearthcomplexes

9.1GradientrefractiveindexdistributionofPOF

9.1.1Qualitativedescriptionofinterfacial-gelpolymerization

9.1.2Diffusionprocessgivenbyfreevolumetheory

9.1.3GradientrefractiveindexdistributionofundopedPOF~

9.1.4GradientrefractiveindexdistributionofrareearthcomplexdopedPOF

9.2DesignandfabricationofSCPOFpreformdopedwithrareearthcomplexes

9.3OpticalamplificationofrareearthcomplexesdopedSIPOF

Postscript

References

　　本书将具有不同结构的稀土掺杂聚合物作为研究对象，从理论和实验的角度对这些聚合物进行了光谱分析、掺杂基质结构设计、发光性质与各层次结构的关系以及光量子调控等多方面的研究，包括各种新颖结构的设计和由其产生的各种特异性质。　　聚合物是通过化学键将小分子连接起来而形成的长链状大分子。由这种分子聚集形成的固体材料具有多层次的物质结构，这些结构会影响掺杂其中的各种功能基团的性质。本书将具有不同结构的稀土掺杂聚合物作为研究对象，从理论和实验的角度对这些聚合物进行了光谱分析、掺杂基质结构设计、发光性质与各层次结构的关系以及光量子调控等多方面的研究，包括各种新颖结构的设计和由其产生的各种特异性质。其中光量子调控是迅速发展的宽带通讯领域的关键技术，相应的基础和应用基础研究已形成一个由聚合物科学和光子学交叉而成的新兴学科光子学聚合物科学。书中介绍的发光调控、三维光学存储和稀土掺杂聚合物光纤的光放大性质等均为光子学聚合物领域的最新进展。虽然本书是非常专业的学术专著，但是通过阅读，读者也能从中了解这一新兴交叉学科的概况。书中还列出了相关原始文献以满足感兴趣的读者进一步了解相关内容的需要。