化工热力学导论

List of SymbolsPrefaceChapter 1 Introduction 1.1 THE SCOPE OF THERMODYNAMICS 1.2 DIMENSIONS AND UNITS 1.3 MEASURES OF AMOUNT OR SIZE 1.4 FORCE 1.5 TEMPERATURE 1.6 PRESSURE 1.7 WORK 1.8 ENERGY 1.9 HEAT KEY NOTES GLOSSARY AND EXPLANATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 2 The First Law and Other Basic Concepts 2.1 JOULE'S EXPERIMENTS 2.2 INTERNAL ENERGY 2.3 THE FIRST LAW OF THERMODYNAMICS 2.4 ENERGY BALANCE FOR CLOSED SYSTEMS 2.5 THERMODYNAMIC STATE AND STATE FUNCTIONS 2.6 EQUILIBRIUM 2.7 THE PHASE RULE 2.8 THE REVERSIBLE PROCESS 2.9 CONSTANT-V AND CONSTANT-P PROCESSES 2.10 ENTHALPY 2.11 HEAT CAPACITY 2.12 MASS AND ENERGY BALANCES FOR OPEN SYSTEMS KEY NOTES GLOSSARY AND EXPLANATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 3 Volumetric Properties of Pure Fluids 3.1 PVT BEHAVIOR OF PURE SUBSTANCES 3.2 VIRIAL EQUATIONS OF STATE 3.3 THE IDEAL GAS 3.4 APPLICATION OF THE VIRIAL EQUATIONS 3.5 CUBIC EQUATIONS OF STATE 3.6 GENERALIZED CORRELATIONS FOR GASES 3.7 GENERALIZED CORRELATIONS FOR LIQUIDS KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 4 Heat Effects 4.1 SENSIBLE HEAT EFFECTS 4.2 LATENT HEATS OF PURE SUBSTANCES 4.3 STANDARD HEAT OF REACTION 4.4 STANDARD HEAT OF FORMATION 4.5 STANDARD HEAT OF COMBUSTION 4.6 TEMPERATURE DEPENDENCE OF ΔH 4.7 HEAT EFFECTS OF INDUSTRIAL REACTIONS KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 5 The Second Law of Thermodynamics 5.1 STATEMENTS OF THE SECOND LAW 5.2 HEAT ENGINES 5.3 THERMODYNAMIC TEMPERATURE SCALES 5.4 ENTROPY 5.5 ENTROPY CHANGES OF AN IDEAL GAS 5.6 MATHEMATICAL STATEMENT OF THE SECOND LAW 5.7 ENTROPY BALANCE FOR OPEN SYSTEMS 5.8 CALCULATION OF IDEAL WORK 5.9 LOST WORK 5.10 THE THIRD LAW OF THERMODYNAMICS KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 6 Thermodynamic Properties of Fluids 6.1 PROPERTY RELATIONS FOR HOMOGENEOUS PHASES 6.2 RESIDUAL PROPERTIES 6.3 RESIDUAL PROPERTIES BY EQUATIONS OF STATE 6.4 TWO-PHASE SYSTEMS 6.5 THERMODYNAMIC DIAGRAMS 6.6 TABLES OF THERMODYNAMIC PROPERTIES 6.7 GENERALIZED PROPERTY CORRELATIONS FOR GASES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 7 Applications of Thermodynamics to Flow Processes 7.1 DUCT FLOW OF COMPRESSIBLE FLUIDS 7.2 TURBINES (EXPANDERS) 7.3 COMPRESSION PROCESSES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 8 Production of Power from Heat 8.1 THE STEAM POWER PLANT 8.2 INTERNAL-COMBUSTION ENGINES 8.3 JET ENGINES，ROCKET ENGINES AND RAMJET ENGINES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 9 Refrigeration and Liquefaction 9.1 THE CARNOT REFRIGERATOR 9.2 THE VAPOR-COMPRESSION CYCLE 9.3 THE CHOICE OF REFRIGERANT 9.4 ABSORPTION REFRIGERATION 9.5 THE HEAT PUMP 9.6 LIQUEFACTION PROCESSES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 10 Vapor/Liquid Equilibrium： Introduction 10.1 THE NATURE OF EQUILIBRIUM 10.2 THE PHASE RULE； DUHEM'S THEOREM 10.3 VLE： QUALITATIVE BEHAVIOR 10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM 10.5 VLE BY MODIFIED RAOULT'S LAW 10.6 VLE FROM K-VALUE CORRELATIONS KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 11 Solution Thermodynamics： Theory 11.1 FUNDAMENTAL PROPERTY RELATION 11.2 THE CHEMICAL POTENTIAL AND PHASE EQUILIBRIA 11.3 PARTIAL PROPERTIES 11.4 THE IDEAL-GAS MIXTURE MODEL 11.5 FUGACITY AND FUGACITY COEFFICIENT： PURE SPECIES 11.6 FUGACITY AND FUGACITY COEFFICIENT： SPECIES IN SOLUTION 11.7 GENERALIZED CORRELATIONS FOR THE FUGACITY COEFFICIENT 11.8 THE IDEAL-SOLUTION MODEL 11.9 EXCESS PROPERTIES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 12 Solution Thermodynamics： Applications 12.1 LIQUID-PHASE PROPERTIES FROM VLE DATA 12.2 MODELS FOR THE EXCESS GIBBS ENERGY 12.3 PROPERTY CHANGES OF MIXING 12.4 HEAT EFFECTS OF MIXING PROCESSES KEY NOTES GLOSSARY AND EXPLAINATIONS CONCEPTUAL PROBLEMS PROBLEMSChapter 13 Chemical-Reaction Equilibria 13.1 THE REACTION COORDINATE 13.2 APPLICATION OF EQUILIBRIUM CRITERIA TO CHEMICAL REACTIONS 13.3 THE STANDARD GIBBS-ENERGY CHANGE AND THE EQ CONSTANT 13.4 EFFECT OF TEMPERATURE ON THE EQUILIBRIUM CONSTANT 13.5 EVALUATION OF EQUILIBRIUM CONSTANTS 13.6 RELATION OF EQUILIBRIUM CONSTANTS TO COMPOSITION 13.7 EQUILIBRIUM CONVERSIONS FOR SINGLE REACTIONS 13.8 PHASE RULE AND DUHEM'S THEOREM FOR REACTING SYSTEMS 13.9 MULTIREACTION EQUILIBRIA KEY NOTES GLOSSARY AND EXPLAINATION CONCEPTUAL PROBLEMS PROBLEMSAppendix A Conversion Factors and Values of the Gas ConstantAppendix B Properties of Pure SpeciesAppendix C Heat Capacities ad Property Changes of FormationAppendix D Representative Computer Programs参考文献

J.M.史密斯教授、H.C.范内斯、M.M.阿博特编著的《化工热力学导论》是世界化工领域影响最大、发行范围最广的化工热力学教材。本书是根据英文原版书《化工热力学导论》第7版改编。改编书选取了原书前13章，内容涵盖了化学工程师专业教育所需的内容。全书主要内容包括以下几个方面：热力学基本概念和基本定律、纯流体的PVT性质、热效应、纯流体的热力学性质、热力学在流动过程中的应用、热力做功、制冷、液化、汽液平衡、溶液热力学理论和应用以及化学反应平衡。这13章内容可以分为三部分：热力学和化学热力学基础(第1-6章)，热力学在工业过程中的应用(第7-9章)，热力学在化学过程中的应用(第10-13章)。书中给出了大量既有理论意义又切合工业实际的例题，并配有大量来自工业实践的习题。 全书行文流畅、图表丰富、通俗易懂，可作为化学工程与工艺及其相关专业的化工热力学教科书，也可以作为相关专业研究人员、工程设计和生产管理技术人员的重要参考书，还可以用作化工专业英语的教材或选读材料。