物理化学 : 第6版

Preface

Chapter 1 THERMODYNAMICS

1.1 Physical Chemistry

1.2 Thermodynamics

1.3 Temperature

1.4 The Mole

1.5 Ideal Gases

1.6 Differential Calculus

1.7 Equations of State

1.8 Integral Calculus

1.9 Study Suggestions

1.10 Summary

Chapter 2 THE FIRST LAW OF THERMODYNAMICS

2.1 Classical Mechanics

2.2 P-V Work

2.3 Heat

2.4 The First Law of Thermodynamics

2.5 Enthalpy

2.6 Heat Capacities

2.7 The Joule and Joule-Thomson Experiments

2.8 Perfect Gases and the First Law

2.9 Calculation of First-Law Quantities

2.10 State Functions and Line Integrals

2.11 The Molecular Nature of Internal Energy

2.12 Problem Solving

2.13 Summary

Chapter 3 THE SECOND LAW OF THERMODYNAMICS

3.1 The Second Law of Thermodynamics

3.2 Heat Engines

3.3 Entropy

3.4 Calculation of Entropy Changes

3.5 Entropy, Reversibility, and Irreversibility

3.6 The Thermodynamic Temperature Scale

3.7 What Is Entropy？

3.8 Entropy, Time, and Cosmology

3.9 Summary

Chapter 4 MATERIAL EQUILIBRIUM

4.1 Material Equilibrium

4.2 Entropy and Equilibrium

4.3 The Gibbs and Helmholtz Energies

4.4 Thermodynamic Relations for a System in Equilibrium

4.5 Calculation of Changes in State Functions

4.6 Chemical Potentials and Material Equilibrium

4.7 Phase Equilibrium

4.8 Reaction Equilibrium

4.9 Entropy and Life

4.10 Summary

Chapter 5 STANDARD THERMODYNAMIC FUNCTIONS OF REACTION

5.1 Standard States of Pure Substances

5.2 Standard Enthalpy of Reaction

5.3 Standard Enthalpy of Formation

5.4 Determination of Standard Enthalpies of Formation and Reaction

5.5 Temperature Dependence of Reaction Heats

5.6 Use of a Spreadsheet to Obtain a Polynomial Fit

5.7 Conventional Entropies and the Third Law

5.8 Standard Gibbs Energy of Reaction

5.9 Thermodynamics Tables

5.10 Estimation of Thermodynamic Properties

5.11 The Unattainability of Absolute Zero

5.12 Summary

Chapter 6 REACTION EQUILIBRIUM IN IDEAL GAS MIXTURES

6.1 Chemical Potentials in an Ideal Gas Mixture

6.2 Ideal-Gas Reaction Equilibrium

6.3 Temperature Dependence of the Equilibrium Constant

6.4 Ideal-Gas Equilibrium Calculations

6.5 Simultaneous Equilibria

6.6 Shifts in Ideal-Gas Reaction Equilibria

6.7 Summary

Chapter 7 ONE-COMPONENT PHASE EQUILIBRIUM AND SURFACES

7.1 The Phase Rule

7.2 One-Component Phase Equilibrium

7.3 The Clapeyron Equation

7.4 Solid-Solid Phase Transitions.

……

Chapter 8 REAL GASES

Chapter 9 SOLUTIONS

Chapter 10 NONIDEAL SOLUTIONS

Chapter 11 REACTION EQUILIBRIUM IN NONIDEAL SYSTEMS

Chapter 12 MULTICOMPONENT PHASE EQUILIBRIUM

Chapter 13 ELECTROCHEMICAL SYSTEMS

Chapter 14 KINFTIC THEORY OF GASES

Chapter 15 TRANSPORT PROCESSES

Chapter 16 REACTION KINETICS

Chapter 17 QUANTUM MECHANICS

Chapter 18 ATOMIC STRUCTURE

Chapter 19 MOLECULAR ELECTRONIC STRUCTURE

Chapter 20 SPECTROSCOPY AND PHOTOCHEMISTRY

Chapter 21 STATISTICAL MECHANICS

Chapter 22 THEORIES OF REACTION RATES

Chapter 23 SOLIDS AND LIQUIDS

Bibliography

Appendix

Answers to Selected Problems

Index

《国外高校优秀化学教材（影印版）：物理化学（第6版）》为高等学校物理化学课程教材。《国外高校优秀化学教材（影印版）：物理化学（第6版）》系统介绍了物理化学的基本原理，内容安排以学生学习为导向。通过清晰解释、逐步推导，提及必要的数学物理知识，并避免较难的数学工具，使学生易于理解。书中含大量例题，各章后安排小结、习题及测试题。 　　《国外高校优秀化学教材（影印版）：物理化学（第6版）》主要内容包括：热力学，热力学第一定律，热力学第二定律，物质平衡，反应的标准热力学函数，理想气体混合反应平衡，单组分的相平衡和表面，真实气体，溶液，非理想溶液，非理想体系反应平衡，多组分的相平衡，电化学，气体的动力学理论，传递过程，反应动力学，量子力学，原子结构，分子电子结构，光谱和光化学，统计力学，反应速率理论，固体和液体。