出版社:清华大学出版社
年代:2013
定价:98.0
本书由于富勒烯和石墨烯分别获得了1996年诺贝尔化学奖和2010年诺贝尔物理奖,加上1991年发现的纳米炭管,引发了世界范围内的纳米科技革命。碳材料无论在科技界还是工业界都是热点,各国投入了大量的财力物力进行研究开发。本书结合作者们在碳材料科学与工程的最新研究成果,重点介绍了碳材料的合成、表征和应用方面的新近进展,深入浅出、图文并茂,适合于广大读者自学或者用作教材。
Pteface
Acknowledgment
CHAPTER 1 Introduction
1.1 Classification of carbon materials
1.2 Nanotexture of carbon materials
1.3 Microtexture of carbon materials
1.4 Specification of carbon materials
1.5 Construction of the present book
References
CHAPTER 2 Carbon Nanotubes: Synthesis and Formation
2.1 Synthesis of carbon nanotubes
2.2 Formation of carbon nanotubes
2.2.1 Formation into yarns
2.2.2 Formation into sheets
2.2.3 Formation into sponges
2.3 Applications of carbon nanotubes
2.4 Concluding remarks
References
CHAPTER 3 Graphene: Synthesis and Preparation
3.1 Preparation through the cleavage of graphite
3.2 Preparation through the exfoliation of graphite
3.2.1 Preparation using graphite oxides
3.2.2 Preparation using graphite intercalation compounds
3.3 Synthesis through chemical vapor deposition
3.4 Synthesis through the organic route
3.5 Preparation through other processes
3.6 Concluding remarks
References
CHAPTER 4 Carbonization Under Pressure
4.1 Carbonization under built-up pressure
4.1.1 Setup for carbonization under pressure
4.1.2 Optical texture and carbonization yield
4.1.3 Particle morphology
4.2 Carbonization under hydrothermal conditions
4.3 Carbonization under supercritical conditions
4.4 Concluding remarks
4.4.1 Temperature and pressure conditions for carbonization
4.4.2 Composition of precursors for the formation of carbon spheres
References
CHAPTER 5 Stress Graphitization
5.1 Graphitization under pressure
5.1.1 Structural change in carbons
5.1.2 Mechanism
5.2 Graphitization in coexistence with minerals under pressure
5.2.1 Coexistence with calcium compounds
5.2.2 Coexistence with other minerals
5.2.3 Mechanism for acceleration of graphitization
5.3 Stress graphitization in carbon/carbon composites
5.3.1 Acceleration of graphitization
5.3.2 Mechanism
5.4 Concluding remarks
5.4.1 Graphitization under pressure
5.4.2 Occurrence of graphite in nature
5.4.3 Stress graphitization in carbon/carbon composites
References
CHAPTER 6 Glass-Iike Carbon: Its Activation and Graphitization
6.1 Activation of glass-like carbon
6.1.1 Glass-Iike carbon spheres
6.1.2 Activation in a flow of dry air
6.1.3 Activation in a flow of wet air
6.1.4 Activation process _
6.1.5 Direct observation of micropores
6.1.6 Two-step activation
6.2 Graphitization of glass-like carbons
6.2.1 Graphitization through melting
6.2.2 Graphitization under high pressure
6.2.3 Graphitization in C/C composites
6.3 Concluding remarks
References
CHAPTER 7 Template Carbonization: Morphology and Pore Control
CHAPTER 8 Carbon Nanofibers Via Electrospinning
CHAPTER 9 Carbon Foams
CHAPTER 10 Nanoporous Carbon Membranes and Webs
CHAPTER 11 Carbon Materials for Electrochemical Capacitors
CHAPTER 12 Carbon Materials in Lithium-ion Rechargeable Batteries
CHAPTER 13 Carbon Materials in Photocatalysis
CHAPTER 14 Carbon Materials for Spilled-oil Recovery
CHAPTER 15 Carbon Materials for Adsorption of Molecules and lons
CHAPTER 16 Highly Oriented Graphite with High Thermal Conductivity
CHAPTER 17 Isotropic High-density Graphite and Nuclear Applications
INDEX
Carbon materials are exceptionally diverse in their preparation, structure, texture, and applications.In Advanced Materials Science and Engineering of Carbon, noted carbon scientist Michio Inagaki and his co-authors cover the most recent advances in carbon materials, including new techniques and processes, carbon materials synthesis, and up-to-date descriptions of current carbon-based materials, trends and applications.Beginning with the synthesis and preparation of nanocarbons, carbon nanotubes, and graphenes, the book then reviews recently developed carbonization techniques, such as templating, electrospinning, foaming, stress graphitization, and the formation of glass-like carbon. The last third of the book is devoted to applications, featuring coverage of carbon materials for energy storage (electrochemical capacitors, lithium-ion rechargeable batteries,and adsorptive storage of hydrogen and methane), for environmental protection (photocatalysis,spilled oil recovery, and adsorption of VOCs, etc.), for thermal management, and for nuclear applications.