臭氧烟气多种污染物协同脱除原理与技术

1 Development of Pollution Control Technology During Coal Combustion

1.1 Introduction

1.2 Existing Air Pollution Control Technologies

1.2.1 Desulfurization Technology

1.2.2 Denitrification Technology

1.2.3 Hg Removal Technology

1.2.4 VOCs Control Technology

1.3 Simultaneous Multi-Pollutants Removal Technology

1.3.1 In-Furnace Multi-Pollutants Emission Control Technology

1.3.2 Flue Gas Multi-Pollutants Emission Control Technology

References

2 Principle of Multi-Pollutants Removal Technology in Flue Gas by Ozone

2.1 Introduction

2.2 Ozone Characteristics

2.3 Ozone Generation Methods

2.3.1 Electrode Type

2.3.2 Feed Gas

2.3.3 Dielectric Material

2.3.4 Mixed Discharges

2.3.5 Pulsed Discharge

2.4 Summary

References

3 Chemical Kinetics and Oxidation Mechanisms Between O3 and

NOx/SO2/Hg

3.1 Introduction on Kinetics Modelling

3.2 Kinetic Modelling Results

3.2.1 Kinetic Modelling Between 03 and NO

3.2.2 Kinetic Modelling Between 03 and Hg

3.3 Oxidation Experimental Results

3.3.1 Experimental Setup

3.3.2 Oxidation Mechanism Between 03 and NO

3.3 3 Oxidation Mechanism Between 03 and SO2

3.3 4 Oxidation Mechanism Between 03 and Hg

3.3.5 Oxidation Mechanism Between 03 and CO

3.4 Competitive Reaction Mechanism Between Different Pollutants

3.4.1 Reaction Competition Between NO and SO2 with Ozone

3.4.2 Reaction Competition Between NO and Hg0 with Ozone

3.5 Summary

References

4 Simultaneous Multi-Pollutants Removal with Ozone and Wet Scrubber

4.1 Introduction

4.2 Experimental Section

4.3 Effect ofpH Value on NO2 Removal

4.4 Effect of Tetravalent-S Components on NO2 Removal

4.4.1 Effect of the Sole SO32-

4.4.2 Effect ofpH with the Existence of Tetravalent-S Components

4.4.3 Effect of the Initial NO2 Concentration

4.5 Simultaneous Removal of SO2 and NO2

4.5.1 Effect of SO2 on NO2 Removal

4.5.2 Effect of NO2 on SO2 Removal

4.6 NOr Wet Removal with Excess Ozone Oxidization

4.7 Simultaneous Desulfurization and Denitrification Scheme Incorporated with

Ozone Oxidization and Dual-Tower Scrubbing

4.8 Summary

References

5 Application and Economic Analysis of the Multi-Pollutants Removal

Technology Incorporated with Ozone Oxidization and Alkali Solution

Adsorption

5.1 Application Scheme of O3 and FGD

5.2 Economic Analysis of the Ozone Generation Technology

5.3 Economic Analysis of the 03 and FGD System

5.4 Summary

References

Index

王智化等著的《臭氧烟气多种污染物协同脱除原理与技术(英文版)(精)》总结了现有多种污染物脱除技术的现状，创新性的提出了臭氧氧化烟气的多种污染物协同脱除新技术，通过化学反应动力学方法揭示了臭氧与各种污染物之间的反应动力的机理和过程，并通过试验加以验证。通过氧化产物的回收综合利用，多脱工艺流程、技术经济分析的介绍为臭氧多脱产业化应用提供了理论基础。本专著可供工程热物理、热能工程、化学工程等领域的研究者和工程技术人员，以及高等院校相关专业的师生参考使用。

该书总结了现有多种污染物脱除技术的现状，创新性的提出了臭氧氧化烟气的多种污染物协同脱除新技术，通过化学反应动力学方法揭示了臭氧与各种污染物之间的反应动力的机理和过程，并通过试验加以验证。通过氧化产物的回收综合利用，多脱工艺流程、技术经济分析的介绍为臭氧多脱产业化应用提供了理论基础。本书的特色即是从反应的机理到试验的验证，再到工业应用前期方案的设计进行了分析归纳，可为燃煤锅炉烟气中污染物脱除提供极有价值的参考。