热分析应用手册

应用一览表 Applications List!

1.热分析概论IntroductionTo Thermal Analysis

1.1 差示扫描量热法Differential Scanning Calorimetry(DSC)

1.1.1 常规DSC Conventional DSC

1.1.2 温度调制DSC Temperature－modulated DSC

1.2 热重分析了hermo Gravimetric Analysis(TGA)

1.3 热机械分析了hermo Mechanical Analysis(TMA)

1.4 动态热机械分析Dynamic Mechanical Analysis(DMA)

1.5 与TGA的同步测量SimuLTaneous Measurements with Tga

1.5.1 同步DSC和差热分析Simultaneous DSC and differential thermal analysis(DTA，SDTA

1.5.2 逸出气体分析Evolved gas analysis(EGA)

1.5.2.1 TGA－MS

1.5.2.2 TGA－FTIR

2.弹性体的结构、性能和应用Structure.Properties and Applications of Elastomers

2.1 聚合物的结构Structure of Polymers

2.1.1 大分子中单体的排列Arrangement of monomers in a macromolecule

2.1.2 大分子的结构Structure of macromolecules

2.2 聚合物的物理结构Physical Structure of Polymers

2.3 聚合物材料的分类Classification of Polymeric Materials

2.4 弹性体产品Elastomeric Products

2.4.1 聚合物的交联Cross－linking of polymers

2.4.2 弹性体的生产Manufacture of elastomers

2.4.3 弹性体的组成Composition of elastomers

2.5 弹性体的分类Classfication of Elastomers

2.6 弹性体实例Examples of Elastomers

2.7 弹性体分析Analysis of Elastomers

2.7.1 热效应了hermal effects

2.7.2 应用概述Application overview

2.7.3 弹性体分析标准方法汇总Summary of standard methods for elastomer analysis45

3.弹性体的基本热效应BasicThermal Effects of Elastomers

3.1 DSC测试效应Measurement Effects with DSC

3.1.1 玻璃化转变的计算方法Evaluation of glass transitions

3.1.2 结晶和熔融Crystallization and melting

3.1.3 硫化反应Vulcanization reaction

3.1.4 借助ADSC用于曲线解析了he use of ADSC to aid curve intcrprctati.n93

3.2 效应的TGA测量Measurement Effects with TGA

3.2.1 组分分析的基本原理Basic principles of compositional analysis

3.2.2 实验条件的影响Influence of experimental conditions

3.2.3 计算方法Evaluation possibilities

3.3 TMA测量TMA Measurements

3.3.1 膨胀系数的测量Measurement of the expansion coefficient

3.4 DMA实验DMA Experiments

3.4.1 复合力学性能The complex mechanical properties

3.4.2 DMA曲线的计算和表示Evaluation and presentation of DMA curves

3.4.3 玻璃化转变和松弛Glass transition and relaxation

4.热分析的应用Applications.f Thermal Analysis

4.1 橡胶的分析Analysis of Rubber

4.1.1 不同种类橡胶的TGA分析TGA analysis of different types of rubber

4.1.2 玻璃化转变Glass transition

4.1.3 结晶和熔融Crystallization and melting

4.1.4 DSC和DMA测量的比较Comparison of DSC and DMA measurements

4.2 硫化Vulcanization

4.2.1 硫化反应Vulcanization reactions

4.2.2 SBR硫化度对其热分析结果的影响Influence of the degree of vulcanization.n thc resultS of SBR

4.2.3 硫化和未硫化硅橡胶的DSC比较Comparison of vulcanized and unvulcanized silic.nc elastomers by DSC

4.3 碳黑的影响The Influence of Carbon Black

4.3.1 碳黑的分析Analysis of carbon black

4.3.2 测定碳黑对弹性体影响的DSC测量DSC measurements tO determine the effect.f carb.n black on elastomers

4.3.3 弹性体中碳黑的TGA分析Analysis of carbon black in elastomers byTGA

4.3.4 含碳黑填料弹性体的TMA测量TMA of elastomers with carbon black fillers

4.3.5 碳黑填充弹性体的DMA测量Measurement of carbon black filled elastomers by DMA

4.4 以单一聚合物为基础的弹性体的实验Experiments on Elastomers Based on a Single Type Polymer

4.4.1 TGA分析TGA Analysis

4.4.2 弹性体的气体分析鉴别Identification of elastomers by means of gas analysis

4.4.3 DSC测量DSC Measurements

4.4.4 低分子量成分的熔融和结晶Melting and crystallization of low molecular weight components

4.5 含若干个聚合物成分的弹性体Elastomers with Several Polymer Components

4.5.1 TGA测量TGA Measurements

4.5.2 弹性体组分的TGA／FTIR鉴定Identification of the polymer constituents byTGA－FTIR

4.5.3 DSC测量DSC measurements

4.5.4 复杂弹性体的分析实例Example of a complex elastomer analysis

4.5.5 DMA测量DMA measurements

4.6 弹性体中油和增塑剂的分析Analysis of Oils And Plasticizers In Elastomers

4.6.1 油含量的TGA测定Determination of the oil content by TGA

4.6.2 增塑剂对玻璃化转变的影响Influence of plasticizers on the glass transition

4.7 添加剂和助剂的分析Analysis of Additives and Auxiliary Agents

4.7.1 阻燃剂Flame retardants

4.7.2 增塑剂Plasticizers

4.8 弹性体的进一步测量Further Measurements of Elastomers

4.8.1 TMA测量TMA measurements

4.8.2 DSC测量DSC measurements

5.结果的总结Summary of Results

参考文献Literature

《弹性体》是《热分析应用手册系列丛书》分册。本分册通过大量实例全面深入地介绍和讨论了热分析在聚合物弹性体方面的应用。第工至第3章为热分析方法简介，弹性体的结构、性能和应用；弹性体的基本热效应。第4至第5章介绍了大量的应用实例，包括对结果的详细解释和导出的结论。