基础化学

Chapter 1 Introduction

1.1 History of Chemistry

1.2 Chemistry in Medicine

1.3 Measurement of Matter： the SI Unit

1.4 Quantitative Ways of Expressing Concentration

1.5 Chapter Summary

Review Questions

Answers

References

Chapter 2 Colligative Properties of Dilute Solutions

2.1 Vapor Pressure Lowering

2.2 Boiling Point Elevation and Freezing Point Depression

2.3 Osmotic Pressure

2.4 Chapter Summary

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References

Chapter 3 Solution Electrolyte

3.1 Theory of Strong Electrolyte Solution

3.2 Proton Theory of Acids and Bases

3.3 Calculating the pH of Acid and Base Solution

3.4 Chapter Summary

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References

Chapter 4 Buffer Solution

4.1 Buffer Solution and How a Buffer Works

4.2 Calculating the pH of a Buffer Solution

4.3 Buffer Capacity and Buffer Range

4.4 Preparing Buffer Solutions

4.5 Buffer Solution in Human Blood

4.6 Chapter Summary

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References

Chapter 5 Equilibria of Sparingly Soluble Ionic Compounds

5.1 The Solubility Product Constant， Ksp

5.2 The Relationship between Solubility and Ksp

5.3 Predicting the Formation of a Precipitate： Q vs. Ksp

5.4 Equilibria Shift

5.5 Application of Ionic Equilibria to Medicine

5.6 Chapter Summary

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Chapter 6 Colloids and Emulsions

6.1 Introduction

6.2 Colloid

6.3 Sol

6.4 Polymer Solution

6.5 Chapter Summary

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Chapter 7 Chemical Thermodynamics

7.1 The First Law： The Concepts

7.2 The Extent of Chemical Reactions

7.3 Indirect Determination of AH： Hess's Law

7.4 Energy Values of Food

7.5 Chapter Summary

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Chapter 8 The Direction and of Chemical Reactions Equilibrium

8.1 Spontaneity： The Meaning of Spontaneous Change

8.2 Entropy and Entropy Change

8.3 Free Energy and Free Energy Change

8.4 Standard Free Energy Change， AGe

8.5 Relationship of AGe to AG for Nonstandard Conditions

8.6 Relationship ofAGe to the Equilibrium Constant Ke

8.7 Criteria for Spontaneous Change

8.8 Altering Equilibrium Conditions： Le Ch~terlier's Principle

8.9 The Le Chfitelier's Principle in Physiology

8.1 0 Chapter Summary

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Chapter 9 Kinetics： Rates and Mechanisms of Chemical Reactions

9.1 The Rates of Chemical Reactions

9.2 Rate Laws and Reaction Order

9.3 Rate Constant and Reaction Order

9.4 Reaction Mechanisms： Steps in the Overall Reaction

9.5 Theoretical Models for Chemical Kinetics

9.6 The Effect of Temperature on Reaction Rates

9.7 Catalysis

9.8 Chapter Summary

Review Questions

Chapter 10 Electrochemistry

10.1 Oxidation-Reduction Reactions

10.2 Voltaic Cell

10.3 Electrode Potentials

10.4 Free Energy and Electrical Work

10.5 Predicting Spontaneous Reactions for Nonstandard Conditions

10.6 Chapter Summary

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Chapter 11 Atomic Structure and Periodical Table

11.1 The Discovery of Atomic Structure

11.2 Atomic Spectrum and the Bohr Model of the Atom

11.3 The Wave-Particle Duality of Matter and Energy

11.4 The Atomic Orbital and the Probable Location of the Electron

11.5 Quantum Numbers and Electron Orbitals

11.6 Electron Configurations

11.7 The Periodic Law and the Periodic Table

11.8 Chapter Summary

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Chapter 12 Covalent and Intermolecular Forces Bonding

12.1 The Covalent Bonding Model

12.2 Hybridization of Atomic Orbitals

12.3 Molecular Orbital （MO） Theory

12.4 Delocalized Electrons： Bonding in the Benzene Molecule

12.5 Intermolecular Forces

12.6 Chapter Summary

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Chapter 13 Chemistry Compounds of Coordination

13.1 The Structure of Complexes

13.2 Formulas and Names of Coordination Complexes

13.3 Isomerism

13.4 Chemical Bond Theories of Complexes

13.5 Aspects of Complex-Ion Equilibrium

13.6 Metals and Chelates in Living Systems

13.7 Chapter Summary

Review Questions

Chapter 14 Acid-Base Titration

14.1 Getting Started： Some Terminology

14.2 Significant Figures

14.3 Acid-Base Indicator

14.4 Titration of a Strong Acid with a Strong Base

14.5 Titration of a Weak Acid with a Strong Base

14.6 Standardization of Acid （Base） Using a Primary Standard

14.7 Chapter Summary

Review Questions

Chapter 15 Absorption Spectroscopy UV-Vis

15.1 UV-Vis Spectroscopic Regions

15.2 Beer-Lambert Law

15.3 UV/Vis Absorbance Bands and Structures

Review Questions

Notes

Index

Appendix A--H

《基础化学（英文版）》以英文的形式介绍了化学的基础知识，内容涉及溶液理论、酸碱平衡理论、重量分析法、滴定分析法、酸碱滴定法、非水滴定法、配位滴定法、沉淀滴定法、氧化还原滴定、比色分析及分光光度法、物质结构基础、烷烃与环烷烃、烯烃与炔烃、芳香烃与卤代烃、醇、酚、醚，醛和酮、羧酸及其衍生物、含氮有机化合物、杂环化合物。可应用于高职高专环境工程、化学分析、应用化工、煤化工等专业，也可应用于资源环境、生物工程、制药等专业以及在职职工的培训。