伏安法教程题解

Publisher's Foreword

Glossary of Symbols and Abbreviations

1 Equilibrium Electrochenustry and the Nernst Equation

1.1 CeIIThermodynamics

1.2 TheNernstEquation

1.3 TheNernstEquation

1.4 TheNernstEquation

1.5 Theory ofthe Nernst Equation

1.6 The Debye-HuckeILimiting Law

1.7 CeIIReaction and Equilibrium Constant

1.8 CelIReaction and Equilibrium Constant

1.9 CelIReaction and Solubility Product

1.10 CeIIReaction andpKa

1.11 CeIIThermodynamics and Temperature

1.12 CellThermodynamics andTemperature

1.13 CeIIEnergetics

1.14 CeIIEMFandpH

1.15 CellReactionandEquilibria

1.16 CelIReaction and Kw

1.17 CeIIReaction and Disproportionation

1.18 FuelCelIEnergetics

1.19 FueICeUEnergetics

1.20 The Influence ofTemperature on the Self-Ionisation ofWater

1.21 CellReaction and Complexation

1.22 Reference Electrodes

1.23 FormalPotentials

1.24 FormaIPotentials

1.25 StandardPotentialsandpH

1.26 StandardPotentials andpH

1.27 Standard Potentials andpH

2 ElectrodeKinetics

2.1 Faraday's Laws ofElectrolysis

2.2 Electrodeposition

2.3 TafeIAnalysis: One-Electron Processes

2.4 TafelAnalysis:ElectrochemicallyReversibleProcesses

2.5 TafeIAnalysis:Mass Transport Correction

2.6 TafeIAnalysis:Two-Electron Processes

2.7 The Butler-Volmer Equation and the Nernst Equation

2.8 The Hydrogen Evolution Reaction

2.9 Requirement for Supporting Electrolyte

2.10 Frumkin Corrections

2.11 Marcus Theory and Standard Electrochemical Rate Constants

2.12 Marcus Theoryand Butler-Volmer Kinetics

2.13 Marcus Theory and the Role ofSolvent

2.14 Marcus Theory and thelnverted Region

3 Diffusion

3.1 Fick's LawsofDiffusion

3.2 Fick's Laws ofDiffusion

3.3 DiffusionDistances

3.4 TheCottrelIEquation

3.5 Derivation ofthe CottreIIEquation

3.6 Diffusion and Root-Mean-Square Displacement

4 CyclicVoltammetry at Macroelectrodes

4.1 CyclicVoltammetry: Electrochemically Reversible Voltammetry

4.2 CyclicVoltammetry:Electrochemicallylrreversible Voltammetry

4.3 ReversiblevsIrreversibleVoltammetry

4.4 VoltammetricDiagnostics

4.5 VoltammetryandScan RateEffects

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《伏安法教程题解》是作者《伏安法教程》的同步习题和解答，为学习伏安法的读者在广阔的理论和实验背景上呈现了大量的习题并给出解答。《伏安法教程题解》的前几章专注于热动力学、电子输运和扩散的基础理论；紧接着是伏安测量实验和分析，包括大量的宏观和微观伏安法的扩展问题；剩下的章节是有关对流、流体力学电极、均相动力学、吸附和电分析应用等。